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In 1959, physicist Richard Feynman presented an
amazing talk entitled There's Plenty of Room at the Bottom, in which he proposed making very small circuits out of molecules. More than forty years later, people are starting to realize his vision. Thanks to Scanning Tunneling Microscope (STM) probes and "self-assembly" fabrication techniques, it is now possible to connect electrodes to a molecule and measure its conductance. In 2004, Mark Hersam et al. reported the first experimental measurement of a molecular resonant tunneling device on silicon. This new field of Molecular
Electronics may someday provide the means to miniaturize circuits beyond the limits of silicon, keeping Moore's Law in force for many years to come.
Learn more about molecular electronics from the resources on this site, listed below. More information on Molecular electronics can be found here.
Chemically Enhanced Carbon-Based Nanomaterials and Devices
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09 Nov 2010 | Online Presentations | Contributor(s): Mark Hersam
Carbon-based nanomaterials have attracted significant attention due to their potential to enable and/or improve applications such as transistors, transparent conductors, solar cells, batteries, and …
MCW07 Exploring Trends in Conductance for Well-Defined Single Molecule Circuits
04 Apr 2009 | Online Presentations | Contributor(s): Mark S Hybertsen
In our recent research, we have been able to measure and characterize the impact of intrinsic molecular properties on the conductance of single molecule circuits formed with amine-gold linkages. In …
MCW07 A Quantum Open Systems Approach to Molecular-Scale Devices
25 Feb 2008 | Online Presentations | Contributor(s): Yongqiang Xue
Experimental advances in electrically and optically probing individual molecules have provided new insights into the behavior of single quantum objects and their interaction with the nanoenvironments …
MCW07 Physics of Contact Induced Current Asymmetry in Transport Through Molecules
25 Feb 2008 | Online Presentations | Contributor(s): Bhaskaran Muralidharan, Owen D. Miller, Neeti Kapur, Avik Ghosh, Supriyo Datta
We first outline the qualitatively different physics involved in the charging-induced current asymmetries in molecular conductors operating in the strongly coupled (weakly interacting) …
Exploring Physical and Chemical control of molecular conductance: A computational study
31 Jan 2008 | Online Presentations | Contributor(s): Barry D. Dunietz
Can numerical “experiments” INSPIRE physical experiments?
20 Dec 2007 | Online Presentations | Contributor(s): Supriyo Datta
This presentation was one of 13 presentations in the one-day forum, "Excellence in Computer Simulation," which brought together a broad set of experts to reflect on the future of computational …
An Experimentalists’ Perspective
19 Dec 2007 | Online Presentations | Contributor(s): Arunava Majumdar
MCW07 Modeling Molecule-Assisted Transport in Nanotransistors
06 Nov 2007 | Online Presentations | Contributor(s): Kamil Walczak
Molecular electronics faces many problems in practical device implementation, due to difficulties with fabrication and gate-ability. In these devices, molecules act as the main conducting channel. …
MCW07 Impact of Porphyrin Functional Groups on InAs Gas Sensors
05 Nov 2007 | Online Presentations | Contributor(s): Michael Garcia
Porphyrin molecules are often used for sensor engineering to improve sensitivity and selectivity to specific analytes. It is important to understand how the porphyrin HOMO-LUMO levels deplete …
Computing the Horribleness of Soft Condensed Matter
19 Oct 2007 | Online Presentations | Contributor(s): Eric Jakobsson
A great triumph of computer simulations 40 years ago was to make the liquid state of matter understandable in terms of physical interactions between individual molecules. Prior to the first …
Energy-level Alignment of Aryl Thiols Chemisorbed on Metal Surfaces: Implications for Molecular Electronic Junctions
27 Sep 2007 | Online Presentations | Contributor(s): Roger D. van Zee
Charge-transport through the interface is a key part of the behavior of any electronic junction. One interface property important to molecular-electronic junctions is the energetic mismatch between …
MCW07 Simple Models for Molecular Transport Junctions
13 Sep 2007 | Online Presentations | Contributor(s): Misha Galperin, Abraham Nitzan, Mark A. Ratner
We review our recent research on role of interactions in molecular transport junctions. We consider simple models within nonequilibrium Green function approach (NEGF) in steady-state regime.
MCW07 Conductance Switching in Fluorene/TiO2 Molecular Heterojunctions
13 Sep 2007 | Online Presentations | Contributor(s): Richard L. McCreery
Molecular junctions consisting of a monolayer of fluorene and 10 nm of TiO2 between conducting contacts exhibit a memory effect upon positive polarization of the of the TiO2 for a few milliseconds. …
MCW07 Molecular Electronics and the Bottom-up View of Electronic Conduction
12 Sep 2007 | Online Presentations | Contributor(s): Supriyo Datta
Molecular electronics is commonly associated with the bottom-up approach to nanofabrication. My objective in this talk is to point out how it also leads to a bottom-up view of electronic conduction …
MCW07 Silicon Based Nanopore Sensors for Detection of DNA Molecules
11 Sep 2007 | Online Presentations | Contributor(s): Samir Iqbal, Demir Akin, Rashid Bashir
Solid-state nanopores have emerged as possible candidates for next-generation DNA sequencing devices. In this talk, we will review our recent work in development of solid-state nanopore channels that …
MCW07 Electronic Level Alignment at Metal-Molecule Contacts with a GW Approach
05 Sep 2007 | Online Presentations | Contributor(s): Jeffrey B. Neaton
Most recent theoretical studies of electron transport in single-molecule junctions rely on a Landauer approach, simplified to treat electron-electron interactions at a mean-field level within density …
MCW07 Modeling Charging-based Switching in Molecular Transport Junctions
23 Aug 2007 | Online Presentations | Contributor(s): Sina Yeganeh, Misha Galperin, Mark A. Ratner
We will discuss several proposed explanations for the switching and negative differential resistance behavior seen in some molecular junctions. It is shown that a proposed polaron model is …
Amine Linked Single Molecule Circuits: Systematic Measurements & Understanding
02 Jul 2007 | Online Presentations | Contributor(s): Mark S Hybertsen
Formation and function of well-defined linkages between organic molecules and metallic electrodes has been a key issue in the field of molecular electronics. We recently discovered that the …
Orbital Mediated Tunneling in a New Unimolecular Rectifier
25 May 2007 | Online Presentations | Contributor(s): Robert Metzger, NCN SLC@Northwestern
In 1997 we showed that hexadecylquinolinium tricyanoquinodimethanide is a unimolecular rectifier, by scanning tunneling microscopy and also as a Langmuir-Blodgett (LB) monolayer, sandwiched between …
BNC Annual Research Symposium: Nanoelectronics and Semiconductor Devices
23 Apr 2007 | Online Presentations | Contributor(s): David Janes
This presentation is part of a collection of presentations describing the projects, people, and capabilities enhanced by research performed in the Birck Center, and a look at plans for the upcoming …
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